The reason that people want to see your experience is because it is far more beneficial to you than your education. Yes, it is a good idea to get a college degree. Most employers are going to require it. However, they are also going to assume that your degree did not really get you ready to do the work that they have for you. They expect to train you in the workplace so that you actually know how to work, something that the majority of colleges are never going to teach you.
If you have work experience, they can see that they might not need to do as much training on their end. Perhaps you want to work for the David Kiger shipping company, for instance, in an administrative capacity. If you have already done a similar job for a smaller company, his company will need to do less to get you up to speed in a larger work setting. The job will be similar. This puts you ahead of people with just a degree.
In fact, you are going to find that many positions are only offered to people with experience. If you have not been in the industry for a few years, you cannot even interview for it. You need to find something else that is entry level. You can apply if you want, but you should concentrate on building your work history first so that your resume is stronger.